One thing to add that I forgot is that you have to worry about cleaning up the lock files, this is something extra that persona has but not roaming profiles. Copy the profile with or without the user logged on, and before you do the switch over log the user you're migrating off and do a final sync Then cleanup the lock file (should be fine after the logoff and final sync and but just check in case) and point the user to the new location and get them to log in.
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